Beilstein J. Org. Chem.2021,17, 166–185, doi:10.3762/bjoc.17.17
building blocks for the ternary electrostaticself-assembly, forming well-defined supramolecular assemblies with tunable sizes of 50 to 500 nm. Due to the network of possible chemical reactions for the anthocyanidin and the excited-state dissociation of the photoacid upon irradiation, different ways to
particles, and information on the molecular structure was gained by UV–vis spectroscopy. Isothermal titration calorimetry (ITC) provided information on the thermodynamics and interaction forces in the supramolecular assembly formation.
Keywords: electrostaticself-assembly; hydroxyflavylium
not rely on specific binding motifs. Here, electrostaticself-assembly was shown to yield a variety of supramolecular nanostructures [4][26][27][28][29][30][31][32][33]. We have built the nanoscale assemblies from polyelectrolytes and multiply oppositely charged molecules based on electrostatic
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Graphical Abstract
Scheme 1:
The chemical network of reactions for 4-hydroxyflavylium (left) and the write-lock-erase cycle (rig...
Beilstein J. Org. Chem.2013,9, 118–134, doi:10.3762/bjoc.9.15
chains of proteins [6], to size control of the electrostaticselfassembly of nanoparticles [7]. Also a pH-controlled release of many cyclodextrins in long stacks on polymers, such as polyrotaxanes, combined with mesoporous silica particles was observed [8].
Complex formation with solvent molecules can
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Graphical Abstract
Figure 1:
Crystal structure of heptakis(6-O-triisopropylsilyl)-β-cyclodextrin benzene pyrene solvate; [C105H2...